For learning LabVIEW - <a href="http://www.ni.com/academic/lv_training/how_learn_lv.htm" target="_blank">http://www.ni.com/academic/lv_training/how_learn_lv.htm</a>
For NI Data Acquisition - <a href="http://www.ni.com/dataacquisition/" target="_blank">http://www.ni.com/dataacquisition/</a> or call NI or your local sales engineer.
For learning how to use NI DAQ - <a href="http://zone.ni.com/devzone/cda/tut/p/id/5434" target="_blank">http://zone.ni.com/devzone/cda/tut/p/id/5434</a>
To simply turn a valve on or off would be trivial in LabVIEW if you had the correct hardware. A simple program could be written in a manner of minutes. In fact, one of the shipping examples could be used as is. It's the intergration of this simple program into whatever else is required that is going to take some time and effort.